Education21c

MSc Chemistry

 

 

 

Physical Chemistry

MOLECULAR SPECTROSCOPY

  • Foundations of Spectroscopic Techniques
  • Resonance Spectroscopy

Physical Foundations of Spectroscopic Techniques  By Sayan Bagchi, Chief Scientist, National Chemical Laboratory

This playlist comprehensively covers the physical aspects of molecular spectroscopy. It includes video lectures about rotational, vibration, resonance (nuclear/electron) and electronic Spectroscopy.

 

SPECTROSCOPIC METHODS IN CHEMISTRY

  • Nuclear Magnetic Resonance Spectroscopy

A comprehensive course in NMR spectroscopic techniques which covers fundamental aspects of this technique to very advanced topics. This can be used as a resource to study and brush up fundamentals of this topic.

A detailed course. It describes mainly proton NMR (1H-NMR) and introduced problem solving in 1H-NMR.

Important concepts for problem solving

NMR Practice-Problem Solving:

SPECTROSCOPIC METHODS IN CHEMISTRY

  • UV-Vis Spectroscopy/Electronic Spectroscopy




Primer:UV-Vis Spectroscopy

Full Course

SPECTROSCOPIC METHODS IN CHEMISTRY

  • Circular Dichroism

Primer:Circular Dichroism

SPECTROSCOPIC METHODS IN CHEMISTRY

  • Infra-Red Spectroscopy

Fundamentals

MOLECULAR SYMMETRY




  •  Symmetry elements and symmetry operation
  1. NPTEL video lectures titled “Symmetry and Group Theory” by Prof. Anindya Datta, IIT Bombay (Lecture 1)
  2. NPTEL video lectures titled “Chemical Applications of Symmetry and Group Theory” by Prof. Manabendra Chandra, IIT Kanpur (Lectures 1 to 4)
  • Point groups. Conditions for a set of elements to form a group.
  1. NPTEL video lectures titled “Symmetry and Group Theory” by Prof. Anindya Datta, IIT Bombay (Lectures 2 to 5)
  2. NPTEL video lectures titled “Chemical Applications of Symmetry and Group Theory” by Prof. Manabendra Chandra, IIT Kanpur (Lectures 5 to 10)
  • Matrix representation of symmetry operations. Character of a matrix. Matrix representation of point group.
  1. NPTEL video lectures titled “Symmetry and Group Theory” by Prof. Anindya Datta, IIT Bombay (Lectures 6 to 8)
  2. NPTEL video lectures titled “Chemical Applications of Symmetry and Group Theory” s by Prof. Manabendra Chandra, IIT Kanpur (Lectures 16 to 18)
  • Multiplication of operations. Group multiplication table.
  1. NPTEL video lectures titled “Symmetry and Group Theory” by Prof. Anindya Datta, IIT Bombay (Lectures 9 to 11)
  2. NPTEL video lectures titled “Chemical Applications of Symmetry and Group Theory” s by Prof. Manabendra Chandra, IIT Kanpur (Lectures 11)
  • Similarity transformation and classification of symmetry operation.
  1. NPTEL video lectures on point groups by Prof. Anindya Datta, IIT Bombay (Lectures 12 to 14; Lectures 17 to 19)
  2. NPTEL video lectures titled “Chemical Applications of Symmetry and Group Theory” s by Prof. Manabendra Chandra, IIT Kanpur (Lectures 12 to 13) 
  •  Reducible and Irreducible representations.
  1. NPTEL video lectures on point groups by Prof. Anindya Datta, IIT Bombay (Lecture 27)
  2. NPTEL video lectures on reducible and irreducible representations by Prof. Manabendra Chandra, IIT Kanpur (Lectures 19 to 20)
  • The Great Orthogonality theorem. Rules derived from GOT (proof not required).
  1. NPTEL video lectures on point groups by Prof. Anindya Datta, IIT Bombay (Lecture 28)
  2. NPTEL video lectures on GOT by Prof. Manabendra Chandra, IIT Kanpur (Lectures 21 to 23)
  3.  
  •  Setting up of character table of C2v, C3v and C2h groups.
  1. NPTEL video lectures on point groups by Prof. Anindya Datta, IIT Bombay (Lectures 29 to 30)
  • Direct product representations.
  1. Reduction formula, reduction of reducible representation to IRs.- Video on Symmetry: IR and Raman Spectroscopy by Melissa Garrett
  •  Transformation properties of atomic orbitals. Hybridisation
  1. NPTEL video lectures on Electronic Transitions by Prof. Manabendra Chandra, IIT Kanpur (Lectures 36 to 38)
  • Molecular symmetry and optical activity.
  1. Video on MO Diagrams chirality polarity by Melissa Garrett

CHEMICAL KINETICS

(Based on the syllabus video lectures are provided mainly from 3 different sources)

  • Introduction to reaction kinetics
  1. MIT lecture by Moungi Bawendi, Keith Nelson
  2. MIT lecture by Catherine Drennan
  •  Complex reactions and mechanisms
  1. MIT lecture by Moungi Bawendi, Keith Nelson
  2. NPTEL lectures on rate processes by Prof. Halder, IIT Kharagpur
  •  Steady-state and equilibrium approximations
  1. MIT lecture by Moungi Bawendi, Keith Nelson
  • Kinetics: Reaction Mechanisms
  1. MIT lecture by Catherine Drennan
  • Arrhenius equation and its limitations, effect of temperature, activated complex
  1. MIT lecture by Catherine Drennan
  •  Theories of reaction rates
  1. NPTEL lectures on rate processes by Prof. Halder, IIT Kharagpur (2 lectures on fast reactions and 2 lectures on ultrafast processes)
  • Kinetics of fast reactions
  1. NPTEL lectures on rate processes by Prof. Halder, IIT Kharagpur (4 lectures)
  •  Reactions in solution
  1. NPTEL lectures on rate processes by Prof. Halder, IIT Kharagpur (2 lectures)

Additional lectures on topics related to Chemical Kinetics

  • Catalysts: Temperature dependence, activation energy
  1. MIT lecture by Catherine Drennan
  2. MIT lecture by Moungi Bawendi, Keith Nelson
  • Nuclear Chemistry and Chemical Kinetics
  1. MIT lecture by Catherine Drennan
  • Chain reactions and explosions
  1. MIT lecture by Moungi Bawendi, Keith Nelson

BASICS OF CHEMICAL THERMODYNAMICS

(Video lectures are provided mostly based on the syllabus)




  • Zeroth law, equation of state

MIT lecture by Moungi Bawendi, Keith Nelson

  • First law: work and heat

MIT lecture by Moungi Bawendi, Keith Nelson

  • First law: Internal energy, expansion work

MIT lecture by Moungi Bawendi, Keith Nelson

  • First law: Enthalpy

MIT lecture by Moungi Bawendi, Keith Nelson

  • Second law

MIT lecture by Moungi Bawendi, Keith Nelson

  • Second law: Entropy and the Clausius inequality

MIT lecture by Moungi Bawendi, Keith Nelson

  • Second law: Entropy and irreversibility

MIT lecture by Moungi Bawendi, Keith Nelson

  •  Third law: Fundamental equation, absolute entropy

MIT lecture by Moungi Bawendi, Keith Nelson

  •  Criteria for spontaneous change

MIT lecture by Moungi Bawendi, Keith Nelson

  • Gibbs free energy: Standard free energy of formation, Free energy functions.

MIT lecture by Moungi Bawendi, Keith Nelson

  •  Chemical potential

MIT lecture by Moungi Bawendi, Keith Nelson

  • Chemical equilibrium

MIT lecture by Moungi Bawendi, Keith Nelson

  • Temperature, pressure and Kp: Variation of Equilibrium constant with temperature and pressure.

MIT lecture by Moungi Bawendi, Keith Nelson

  • Clausius-Clapeyron equation: Temperature and pressure dependence

MIT lecture by Moungi Bawendi, Keith Nelson

  • Properties of mixtures: Ideal solutions

MIT lecture by Moungi Bawendi, Keith Nelson

  • Properties of mixtures: Non-ideal solutions

MIT lecture by Moungi Bawendi, Keith Nelson

  • Properties of mixtures: Colligative properties

MIT lecture by Moungi Bawendi, Keith Nelson

  • Additional NPTEL lectures of the same topics can be seen in the link provided below

 Introduction to Chemical Thermodynamics and Kinetics by Prof. Arijit Kumar De, IISER Mohali